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TB-500 (Thymosin Beta-4 Fragment 17–23)

Identification

Property Value
Full Name Thymosin Beta-4 fragment (17–23), synthetic
Sequence Leu-Lys-Lys-Thr-Glu-Thr-Gln (LKKTETQ)
Source Synthetic analog of the actin-binding domain (residues 17–23) of Thymosin Beta-4
Molecular Formula C₃₈H₆₈N₁₀O₁₄
Molecular Weight ~889 Da
Amino Acid Count 7
Appearance White to off-white lyophilized powder
Solubility Freely soluble in water and aqueous buffers

Biological Context

Thymosin Beta-4 (Tβ4) is a 43-amino acid polypeptide (MW ~4,921 Da) present in most mammalian tissues. It was originally identified as a thymic hormone but is now recognized as the principal G-actin sequestering peptide in eukaryotic cells. The synthetic fragment TB-500 corresponds to the N-terminal actin-binding domain of Tβ4 (residues 17–23, LKKTETQ), which is essential for its actin-polymerization regulatory functions.

The fragment notation "17–23" refers to the amino acid positions within the full Tβ4 sequence, not molecular weight or any other parameter.

Research Applications

Research Domain Description
Cell Migration Promotes directional cell migration (chemotaxis) in fibroblasts, keratinocytes, and endothelial cells; key mediator of wound re-epithelialization
Angiogenesis Stimulates endothelial cell differentiation into capillary-like structures; upregulates VEGF and matrix metalloproteinase expression
Wound Healing Accelerates full-thickness dermal wound closure; increases collagen deposition and wound tensile strength
Actin Polymerization Binds G-actin monomers (Kd ~0.7 μM) and regulates the G-actin/F-actin equilibrium; facilitates localized actin filament assembly at the leading edge of migrating cells
Anti-inflammatory Activity Suppresses neutrophil infiltration and inflammatory cytokine release at injury sites
Cardiac Protection Preclinical models of myocardial infarction show reduced scar size and improved ejection fraction
Hair Follicle Cycling Promotes anagen phase induction and prolongs active growth phase in hair follicle models

Mechanisms of Action

Mechanism Description
Actin Sequestration The LKKTETQ motif binds ATP-G-actin monomers with high affinity, maintaining a pool of polymerization-competent actin for rapid filament assembly
Chemotactic Signaling TB-500 acts as a chemoattractant for endothelial cells, fibroblasts, and keratinocytes, guiding migration toward injury sites
Pro-angiogenic Gene Expression Upregulates VEGF, bFGF, and MMP-2 expression through PI3K/Akt and NF-κB signaling cascades
Anti-apoptotic Effects Reduces caspase-3 activation and increases Bcl-2/Bax ratio in cells subjected to oxidative stress

Quality Specifications

Parameter Specification Method
Purity (HPLC) ≥99.0% RP-HPLC, C18 column, 214 nm
Mass Identity MW ±1.0 Da ESI-MS
Water Content ≤5.0% Karl Fischer titration
Peptide Content ≥80.0% Amino acid analysis
Acetate/TFA Content ≤1.0% (acetate salt) Ion chromatography
Endotoxin ≤1.0 EU/mg LAL kinetic chromogenic
Residual Solvents ≤ ICH Q3C limits Headspace GC
pH (1 mg/mL) 5.0–7.5 Potentiometric

Available Configurations

Format Size Vials per Kit
Standard Research Kit 5 mg × 10 vials 10
Extended Research Kit 10 mg × 10 vials 10
Custom Configuration Bulk/custom Per project

Storage & Stability

Condition Requirement
Short-term Storage 2–8°C, lyophilized form
Long-term Storage −20°C to −80°C, desiccated
Reconstituted 24 h at 2–8°C; aliquot and freeze at −20°C for extended storage
Light Sensitivity Protect from light
Shipping Ambient temperature acceptable for ≤14 days during transit

Documentation

  • COA per batch: HPLC chromatogram, MS spectrum, quantitative purity
  • MSDS supplied with each shipment

Special Notes

  • FOR LABORATORY RESEARCH USE ONLY.
  • TB-500 is a synthetic fragment and is not isolated from biological sources. The product does not contain thymic tissue extracts or any biologically derived raw materials.
  • The G-actin binding affinity of the LKKTETQ fragment is retained at non-physiological pH (5.5–8.5 range), but experimental protocols should consider buffer conditions for optimal activity.
  • As a short linear peptide, TB-500 is susceptible to non-specific adsorption to plastic labware. Use siliconized or low-retention vials and pipette tips for dilute solutions.

Key Research References

Reference PMID Key Finding
Malinda KM et al. "Thymosin β4 accelerates wound healing." J Invest Dermatol. 1999;113(3):364–368. 10469335 Full-length Thymosin Beta-4 significantly accelerates dermal wound closure and increases collagen deposition in vivo
Philp D et al. "Thymosin β4 promotes angiogenesis, wound healing, and hair follicle development." FASEB J. 2004;18(3):439–441. 15037013 Tβ4 promotes endothelial cell migration, capillary tube formation, and hair follicle cycling in rodent models
Sosne G et al. "Thymosin beta 4 promotes corneal wound healing and decreases inflammation in vivo following alkali injury." Exp Eye Res. 2002;74(2):293–299. 11950239 N-terminal LKKTETQ actin-binding domain mediates corneal re-epithelialization and inflammatory modulation

Stability & Storage

Condition Degradation Profile
Neutral pH (5.5–8.5) Stable; the actin-binding affinity of the LKKTETQ fragment is retained across this broad pH range
Repeated Freeze-Thaw Avoid; each freeze-thaw cycle increases risk of peptide degradation, aggregation, and loss of activity. Aliquot into single-use portions after initial reconstitution
Acidic pH (<4.0) Potential hydrolysis of peptide bonds; avoid strongly acidic buffers
Alkaline pH (>9.0) Risk of deamidation at Gln residue; degradation accelerates
Temperature Lyophilized: stable 24 months at 2–8°C, 36 months at −20°C. Reconstituted: 24 h at 4°C; freeze at −20°C for ≤30 days
Light Exposure Protect from light; store in amber vials or opaque containers

Frequently Asked Questions

Q: What purity specifications apply to TB-500?

≥99.0% by HPLC at 214 nm with ESI-MS mass identity confirmation (±1.0 Da). Comprehensive QC includes peptide content (≥80.0%), water content (≤5.0%), acetate/TFA content (≤1.0%), endotoxin (≤1.0 EU/mg), and residual solvents within ICH Q3C limits. Full batch-specific COA with HPLC chromatogram and MS spectrum included.

Q: How should TB-500 be stored after reconstitution?

Reconstituted TB-500 is stable for 24 hours at 2–8°C. For longer storage, aliquot into single-use portions and freeze at −20°C (stable ≤30 days). Critical: avoid repeated freeze-thaw cycles which cause peptide degradation and aggregation. Use siliconized or low-retention vials for dilute solutions — TB-500 is a short linear peptide susceptible to non-specific adsorption to standard plastic labware.

Source & Purchase

For researchers requiring TB 500 with full analytical documentation including HPLC and LC-MS traces, visit the PeptideSourceHub product page for bulk pricing and specifications.

Purchase TB 500 with COA →

Product Link
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